Infrared spectrum and normal coordinate analysis of permanganyl fluoride MnO3F
Identifieur interne : 004851 ( Main/Exploration ); précédent : 004850; suivant : 004852Infrared spectrum and normal coordinate analysis of permanganyl fluoride MnO3F
Auteurs : Martin J. Reisfeld [Mexique] ; Larned B. Asprey [Mexique] ; Nicholas A. Matwiyoff [Mexique]Source :
- Spectrochimica Acta Part A: Molecular Spectroscopy [ 0584-8539 ] ; 1970.
Abstract
This paper presents the infrared spectrum of gaseous MnO3F from 100 to 4000 cm−1. A vibrational analysis is made on the basis of C3v symmetry and valence force constants are determined. The fundamental frequencies of MnO3F are: A1 = 905.2, 720.7, 337.7, E = 952.5, 373.9 and 264.3 cm−1. From the band contours and the zeta sum rule, values for the Coriolis coupling constants are evaluated. The values are: ζ4 = 0.10, ζ5 = −0.03, ζ6 = 0.37. Thermodynamic properties are presented over the temperature range 235–1000°K.
Url:
DOI: 10.1016/0584-8539(71)80153-8
Affiliations:
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<front><div type="abstract" xml:lang="en">This paper presents the infrared spectrum of gaseous MnO3F from 100 to 4000 cm−1. A vibrational analysis is made on the basis of C3v symmetry and valence force constants are determined. The fundamental frequencies of MnO3F are: A1 = 905.2, 720.7, 337.7, E = 952.5, 373.9 and 264.3 cm−1. From the band contours and the zeta sum rule, values for the Coriolis coupling constants are evaluated. The values are: ζ4 = 0.10, ζ5 = −0.03, ζ6 = 0.37. Thermodynamic properties are presented over the temperature range 235–1000°K.</div>
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